| 세션명 | 분자전자 부문위원회 (I) |
|---|---|
| 발표장 | 제1회장 |
| 논문코드 | 1L1-4 |
| 발표일 | 2021-10-21 |
| 발표시간 | 15:15-15:40 |
| 논문제목 | The role of polymer crystalline domain for |
| 발표자 | 박재홍 |
| 발표자 소속 | 이화여자대학교 |
| 저자 | 박재홍† |
| 소속 | 이화여자대학교 |
| 논문초록 | Microstructures of conjugated-polymers in condensed-phase have shown to play important roles on governing the performance of polymer-based optoelectronics. We prepared highly-ordered crystalline poly(3-hexylthiophene) particle (P3HT-CP), made with regioregular P3HT (regioregularity＞99%) by slow antisolvent diffusion method. Various particle characterization data, including SEM and TEM and x-ray diffraction analysis verified the high degree of crystalline formation, revealing continuous crystalline domains extending over 100s nm scale.[1] Electronic absorption spectroscopy and excited-state dynamics based on fluorescence and ultrafast transient absorption spectroscopy for the P3HT-CP will be discussed. These microscopic and optical spectroscopic results suggest enhanced crystallinity in P3HT-CP, which could be a model system to understand exciton dynamics in polymer crystalline domains and the role of polymer microstructures. |
THE POLYMER SOCIETY OF KOREA